Using Pen Tool to crop out items (beginner)
We will do this in four steps.
Step One: Open the selected image you want to remove something from.

Step Two: Zoom In, Select Pen Tool, and start "outlining" the wanted selection.

Step Three: Close Path by returning the path to its start, Then Click on the "Path" Tab next to Layers. Right Click on Work Path Layer, Make Selection, Feather - 0 pixels.
 
Step Four: Now with your Item selected, Copy Selection and either paste on a new layer, or create a new document(will be sized to what is on your clipboard) and put it there!

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